Let's start with some VMware KBTV videos :

Ever wondered what it would be like having VMware issue a new product release and also supply you with great video tutorials on the same day?

Well now you know... here is another video just for you!

This video discusses and demonstrates how you can create a basic virtual machine in vSphere 5 using the vSphere Client.

Additional documentation for the VMware vSphere 5 product is available at:

--> To be seen on  http://blogs.vmware.com/kbtv/2011/08/getting-started-with-vsphere-5-creating-a-basic-virtual-machine-in-vsphere-5-using-the-vsphere-clien.html